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Article Dans Une Revue Macromolecules Année : 2023

Biobased Polyethers via Acyclic Diene Metathesis Polymerization of α,ω-Diene Furanics

Résumé

A new class of furanic α,ω-dienes was synthesized using cellulose-derived 2,5-bis(hydroxymethyl)furan (BHMF) as a renewable starting material. The ability of these monomers to undergo acyclic diene metathesis (ADMET) polymerization was investigated under various reaction conditions, including type of metathesis catalyst and catalyst loading. The resulting bio-based polyethers were characterized through high-performance size exclusion chromatography (HPSEC), differential scanning calorimetry (DSC) and thermal gravimetric analysis (TGA). The novel polymers showed molecular weights up to 43 kDa and exhibited good thermal stability (Td5% > 250 °C) and low glass transition temperatures (-67 °C < Tg < -24 °C). Polymerization reactions were also conducted employing selected green solvents (Cyrene™, dimethyl isosorbide and γ-valerolactone) and the results were compared to the solvent-free procedure. Finally, in order to increase the Tg values of the polyethers, co-polymerization experiments were performed employing the best performing furanic α,ω-diene as well as a bio-based aromatic monomer derived from syringaresinol.
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Dates et versions

hal-04273039 , version 1 (07-11-2023)

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Amandine Flourat, Mattia Annatelli, Sami Fadlallah, Fabio Aricò, Florent Allais. Biobased Polyethers via Acyclic Diene Metathesis Polymerization of α,ω-Diene Furanics. Macromolecules, 2023, ⟨10.1021/acs.macromol.3c01279⟩. ⟨hal-04273039⟩
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